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These items can be found in Horadric Caches. Horadric Caches are rewarded for completing all 5 Bounties for an act in Adventure Mode. Each act drops a different set of Legendaries from this list, Act 4 can drop any of the bounty legendary items. Horadric Caches can also drop non Adventure Mode exclusive legendary items.

Act 1 Caches
Mad Monarch's Scepter

After killing 10 enemies, you release a Poison Nova that deals 1050–1400% weapon damage as Poison to enemies within 30 yards.

One-Handed Mace

Ring of Royal Grandeur

Reduces the number of items needed for set bonuses by 1 (to a minimum of 2).

Ring

Pauldrons of the Skeleton King

When receiving fatal damage, there is a chance that you are instead restored to 25% of maximum Life and cause nearby enemies to flee in fear.

Shoulders

Golden Gorget of Leoric

After earning a massacre bonus, 4–6 Skeletons are summoned to fight by your side for 10 seconds.

Amulet

Sanguinary Vambraces

Chance on being hit to deal 1000% of your Thorns damage to nearby enemies.

Bracers

Act 2 Caches
Coven's Criterion

You take 45–60% less damage from blocked attacks.

Shield

Gloves of Worship

Shrine effects last for 10 minutes.

Gloves

Cloak Of Deception

Enemy missiles sometimes pass through you harmlessly.

Cloak

Illusory Boots

You may move unhindered through enemies.

Boots

Act 3 Caches
Burst Of Wrath

Killing enemies and destroying objects has a chance to grant 20% of your maximum primary resource.

Two-Handed Axe

Boots of Disregard

Gain 500 Life Regeneration per second for each second you stand still. This effect stacks up to 8 times.

Boots

Pride's Fall

Your resource costs are reduced by 30% after not taking damage for 5 seconds.

Helmet

Envious Blade

Gain 100% Critical Hit Chance against enemies at full health.

Dagger

Avarice Band

Each time you pick up gold, increase your Gold and Health Pickup radius by 1 yard for 10 seconds, stacking up to 30 times.

Ring

Insatiable Belt

Picking up a Health Globe increases your maximum Life by 5% for 15 seconds, stacking up to 5 times.

Belt

Overwhelming Desire

Chance on hit to charm the enemy. While charmed, the enemy takes 35% more damage

Amulet

Act 5 Caches
Death’s Bargain

Gain an aura of death that deals 750-1000% of your Life per Second to enemies within 20 yards. You no longer regenerate Life.

Pants

Soulsmasher

When you kill an enemy, it explodes for 450–600% of your Life per Kill as damage to all enemies within 20 yards. You no longer benefit from your Life per Kill.

Two-Handed Mace

Helltrapper

7–10% chance on hit to summon a Spike Trap, Caltrops or Sentry

Hand Crossbow

Salvation

Blocked attacks heal you and your allies for 20–30% of the amount blocked.

Crusader Shield

Pandemonium Loop

Enemies slain while Feared die in a bloody explosion and cause other nearby enemies to flee in Fear.

Ring